Prep the pan and oven. Heat oven to 350°F (175°C). Line a 9x5-inch loaf pan with parchment, leaving overhang for easy lifting.
Lightly grease the sides.
Mix the dry ingredients. In a large bowl, whisk flour, cocoa, sugar, baking powder, baking soda, and salt until evenly combined.
Whisk the wet ingredients. In a separate bowl or large measuring cup, whisk eggs, milk, oil, orange juice, zest, and vanilla until smooth.
Combine. Pour wet into dry. Stir with a spatula until just combined. Do not overmix—a few small lumps are fine.
Add chocolate. Fold in the chopped dark chocolate, reserving a tablespoon to sprinkle on top if you like.
Fill and bake. Pour batter into the pan, smooth the top, and sprinkle the reserved chocolate. Bake for 48–58 minutes, until a toothpick comes out with a few moist crumbs.
Cool. Let the loaf cool in the pan for 10 minutes, then lift out and cool completely on a rack.
Glaze (optional). Whisk powdered sugar, a pinch of salt, and just enough orange juice to make a thick, pourable glaze.
Drizzle over the cooled cake and add zest on top.