Prep the pan: Heat the oven to 375°F (190°C). Line a 12-cup muffin tin with liners or grease lightly.
Mix dry ingredients: In a large bowl, whisk flour, sugar, baking powder, baking soda, salt, cinnamon, and nutmeg.
Mix wet ingredients: In a separate bowl, whisk melted butter, eggs, buttermilk, and vanilla until smooth.
Combine gently: Pour the wet mixture into the dry.
Stir with a spatula just until combined. A few small lumps are fine—don’t overmix.
Fill the cups: Divide batter evenly among the muffin cups, about 3/4 full.
Bake: Bake 15–18 minutes, until the tops spring back and a toothpick comes out clean.
Cool briefly: Let muffins rest in the pan for 5 minutes, then transfer to a rack. While still warm, proceed with coating.
Coat in cinnamon sugar: Stir coating sugar and cinnamon in a shallow bowl.
Brush warm muffins with melted butter (optional) and roll the tops—or the whole muffin—in the mixture.